Lesson 2 2.1 Introduction

Uranium is a dense, silvery-grey metal that is ubiquitous in the Earth’s crust at low concentrations. The following reference table summarises its key physical and nuclear properties.

Table: Key Properties of Uranium

PropertyValue
Atomic number92
Atomic weight238.03 g/mol
Density19.1 g/cm³ (70% denser than lead)
Melting point1,132 °C
Boiling point4,131 °C
Crystal structureOrthorhombic (alpha phase, below 660 °C)
AppearanceSilvery-grey metal; oxidises in air forming a black coating
Natural isotopesU-234 (0.0055%), U-235 (0.711%), U-238 (99.284%)
Crustal abundance2—4 ppm (average); up to 20 wt% in richest deposits
Seawater concentration~3 ppb (~4 billion tonnes total in the world’s oceans)

Uranium is chemically reactive, forming compounds with most non-metallic elements. The most important uranium compounds in the fuel cycle are: UO₂ (the ceramic fuel form), U₃O₈ (yellowcake, the naturally occurring oxide), UF₄ (green salt, an intermediate in conversion), and UF₆ (uranium hexafluoride, used for enrichment). UF₆ sublimes at 56.5 °C, making it convenient for handling as a gas in enrichment cascades. Fluorine has only one natural isotope (F-19), so the mass difference between ²³⁵UF₆ (349 amu) and ²³⁸UF₆ (352 amu) depends solely on the uranium isotopes.