Lesson 3 3.6 Radiological Properties of Fresh Fuel

The main isotopes within unirradiated fuel produced from mined uranium are listed in Table 3.1. These values are for natural uranium; for enriched fuel, the proportions of U-234 and U-235 are increased relative to U-238 (see worked example below).

Table 3.1: Isotopes within Fresh UO2_2 Fuel (Natural Uranium Basis)

IsotopeWeight Fraction (%)Decay ModeHalf-lifeSpecific Activity (Bq/g of isotope)
U-2340.0055Alpha (α\alpha)2.46 ×\times 105^5 years2.31 ×\times 108^8
U-2350.72Alpha (α\alpha)7.04 ×\times 108^8 years8.00 ×\times 104^4
U-23899.27Alpha (α\alpha)4.47 ×\times 109^9 years1.24 ×\times 104^4

Key points:

  • All three isotopes are alpha emitters, which also emit low-energy gamma rays with low abundances
  • Combined with the self-shielding properties of the dense uranium material, the external radiation hazard from fresh fuel is negligibly small
  • Typical surface dose rate: approximately ~20 μ\muSv/h
  • The dominant contribution to the total activity comes from U-234, despite it being present in the smallest proportion. This is because U-234 has a much shorter half-life and therefore a much higher specific activity.

Tip for students: It may seem counter-intuitive that U-234 (only 0.0055% of natural uranium) contributes more to the total activity than U-238 (99.27%). Remember: shorter half-life = higher activity. A small mass of a short-lived isotope can be far more active than a large mass of a long-lived one.