Lesson 4 4.3 Calculating Fission Product Inventories

The general solution above simplifies further depending on whether the half-life is short or long compared to the irradiation time.

SHORT-LIVED APPROXIMATION: T1/2T_{1/2} \ll irradiation time

If the fission product half-life is much shorter than the time the reactor has been operating (e.g. 131^{131}I with T1/2T_{1/2} = 8 days in a reactor running for months), then the exponential term eλte^{-\lambda t} becomes negligibly small (effectively zero), and:

Aeq=R=FY\boxed{A_{\text{eq}} = R = F \cdot Y}

The activity reaches a constant equilibrium value. Production and decay are balanced --- for every atom created by fission, one atom decays. The activity depends only on the fission rate and the yield, not on how long the reactor has been running.

QuantityMeaning
FFFission rate (fissions per second) = Power (watts) ×\times 3.1 ×1010\times 10^{10} fissions/W/s
YYCumulative fission yield (fraction, not percent!)

LONG-LIVED APPROXIMATION: T1/2T_{1/2} \gg irradiation time

If the fission product half-life is much longer than the irradiation time (e.g. 137^{137}Cs with T1/2T_{1/2} = 30.17 years in a reactor running for 1 year), then we can use the approximation eλt1λte^{-\lambda t} \approx 1 - \lambda t (first-order Taylor expansion), giving:

A(t)=R(1eλt)RλtA(t) = R\left(1 - e^{-\lambda t}\right) \approx R \cdot \lambda t

A(t)=FYλt=FY0.693tT1/2\boxed{A(t) = F \cdot Y \cdot \lambda \cdot t = F \cdot Y \cdot \frac{0.693 \cdot t}{T_{1/2}}}

The activity builds up linearly with time. It has not yet begun to approach equilibrium. Longer irradiation gives proportionally more activity.

Summary of Approximations

  • Equilibrium (short-lived) --- When T1/2tirradiationT_{1/2} \ll t_{\text{irradiation}}: Use A=FYA = F \cdot Y. Activity is constant; production equals decay.
  • Linear (long-lived) --- When T1/2tirradiationT_{1/2} \gg t_{\text{irradiation}}: Use A=FYλtA = F \cdot Y \cdot \lambda \cdot t. Activity grows linearly; negligible decay during operation.
  • Full solution (general case) --- When T1/2T_{1/2} is comparable to tirradiationt_{\text{irradiation}}: Use A=R(1eλt)A = R(1 - e^{-\lambda t}).