Lesson 3 3.3 Cladding Properties

Following the 2011 Fukushima accident, there has been considerable interest in safer cladding materials. During the accident, at elevated temperatures the Zircaloy cladding reacted with steam to produce hydrogen gas:

Zr+2H2OZrO2+2H2\text{Zr} + 2\text{H}_2\text{O} \rightarrow \text{ZrO}_2 + 2\text{H}_2

This hydrogen accumulated and caused explosions at the reactor plant. As a result, accident-tolerant fuel (ATF) programmes are now investigating alternative cladding materials such as silicon carbide (SiC) and FeCrAl alloys that do not generate hydrogen under accident conditions.